Summary

  1. An atom has a nucleus. The nucleus is positively charged. The radius of the nucleus is smaller than the radius of an atom by a factor of 104 . More than 99.9% mass of the atom is concentrated in the nucleus.
  2. On the atomic scale, mass is measured in atomic mass units (u). By definition, 1 atomic mass unit (1u) is 1/12th  mass of one atom of 12 C; 1u=1.660563×1027 kg
  3. A nucleus contains a neutral particle called neutron. Its mass is almost the same as that of proton
  4. The atomic number Z is the number of protons in the atomic nucleus of an element. The mass number A is the total number of protons and neutrons in the atomic nucleus; A = Z+N; Here N denotes the number of neutrons in the nucleus.
    A nuclear species or a nuclide is represented as zAX, where X is the chemical symbol of the species.
    Nuclides with the same atomic number Z, but different neutron number N are called isotopes. Nuclides with the same A are isobars and those with the same N are isotones.
    Most elements are mixtures of two or more isotopes. The atomic mass of an element is a weighted average of the masses of its isotopes and calculated in accordance to the relative abundances of the isotopes.
  5. A nucleus can be considered to be spherical in shape and assigned a radius. Electron scattering experiments allow determination of the nuclear radius; it is found that radii of nuclei fit the formula R=R0A1/3 where R0= a constant =1.2fm. This implies that the nuclear density is independent of A. It is of the order of 1017 kg/m3.
  6. Neutrons and protons are bound in a nucleus by the short-range strong nuclear force. The nuclear force does not distinguish between neutron and proton.
  7. The nuclear mass M is always less than the total mass, Σm, of its constituents. The difference in mass of a nucleus and its constituents is called the mass defect. ΔM=(Zmp+(AZ)mn)M Using Einstein's mass energy relation, we express this mass difference in terms of energy as ΔEb=ΔMc2 The energy ΔEb represents the binding energy of the nucleus. In the mass number range A=30 to 170, the binding energy per nucleon is nearly constant, about 8MeV/ nucleon.
  8. Energies associated with nuclear processes are about a million times larger than chemical process.
  9. The Q-value of a nuclear process is Q = final kinetic energy – initial kinetic energy. Due to conservation of mass-energy, this is also, Q=( sum of initial masses  sum of final masses )c2
  10. Radioactivity is the phenomenon in which nuclei of a given species transform by giving out α or β or γ rays; α -rays are helium nuclei; β -rays are electrons. γ rays are electromagnetic radiation of wavelengths shorter than X-rays;
  11. Law of radioactive decay : N(t)=N(0)eλt where λ is the decay constant or disintegration constant. The half-life T1/2 of a radionuclide is the time in which N has been reduced to one-half of its initial value. The mean life τ is the time at which N has been reduced to e1 of its initial value T1/2=ln2λ=τln2
  12. Energy is released when less tightly bound nuclei are transmuted into more tightly bound nuclei. In fission, a heavy nucleus like 235 92 U breaks into two smaller fragments, e.g.,92235U+01n51133Sb+4199Nb+401n
  13. The fact that more neutrons are produced in fission than are consumed gives the possibility of a chain reaction with each neutron that is produced triggering another fission. The chain reaction is uncontrolled and rapid in a nuclear bomb explosion. It is controlled and steady in a nuclear reactor. In a reactor, the value of the neutron multiplication factor k is maintained at 1.
  14. In fusion, lighter nuclei combine to form a larger nucleus. Fusion of hydrogen nuclei into helium nuclei is the source of energy of all stars including our sun.